Verified Solution • 2025–26 Session moderate

QJEEM23Che1f9: JEE Main 2023 Chemistry - Class 12 JEEM23Che1f9 Solution: 25 mL of an aqueous solution of KCl was found to require 20 mL…

25 mL of an aqueous solution of KCl was found to require 20 mL of 1 M AgNO3 solution when titrated using K2CrO4 as an indicator. What is the depression in freezing point of KCl solution of the given concentration? _________ (Nearest integer).

(Given : Kf=2.0 K kg mol−1)

Assume 1) 100% ionization and 2) density of the aqueous solution as 1 g mL−1

Step-by-Step Verified Solution

25×M=20×125 \times M=20 \times 1

M=2025=45=0.8ΔTf=(i)(Kf)(m)=(2)(2)(45)=165=3.2

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