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QJEEM23Chddb6: JEE Main 2023 Chemistry - Class 12 JEEM23Chddb6 Solution: Mass of Urea required to be dissolved in of water in order to…

Mass of Urea (NH2CONH2)\left(\mathrm{NH}_{2} \mathrm{CONH}_{2}\right) required to be dissolved in 1000 g1000 \mathrm{~g} of water in order to reduce the vapour pressure of water by 25%25 \% is _________ g. (Nearest integer)

Given: Molar mass of N, C, O and H are 14,12,1614,12,16 and 1 g mol−11 \mathrm{~g} \mathrm{~mol}^{-1} respectively

Step-by-Step Verified Solution

Given:

  • Vapor pressure reduction: 25%25\% ( 0.750.75 times the vapor pressure of pure water)

  • Molar mass of water ( H2O\text{H}_2\text{O} ): 18 g/mol18 \, \text{g/mol}

  • Mass of solvent (water): 1000 g1000 \, \text{g}

Using Raoult's law:

P0−PsPs=nsolutensolvent=xMurea1000Mwater=P0−0.75P00.75P0\frac{P^0 - P_s}{P_s} = \frac{n_{\text{solute}}}{n_{\text{solvent}}} = \frac{\frac{x}{M_{\text{urea}}}}{\frac{1000}{M_{\text{water}}}} = \frac{P^0 - 0.75P^0}{0.75P^0}

Solving for (x):

x60=100009\frac{x}{60} = \frac{10000}{9} x=1111.11111≈1111 gx = 1111.11111 \approx 1111 \, \text{g}

So, the mass of urea required to be dissolved in 1000 g1000 \, \text{g} of water is 1111 g1111 \, \text{g} .

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