Verified Solution • 2025–26 Session moderate

QJEEM23Chbf32: JEE Main 2023 Chemistry - Class 12 JEEM23Chbf32 Solution: Which halogen is known to cause the reaction given below :

Which halogen is known to cause the reaction given below :

2Cu2++4X−→Cu2X2(s)+X22 \mathrm{Cu}^{2+}+4 \mathrm{X}^{-} \rightarrow \mathrm{Cu}_{2} \mathrm{X}_{2}(\mathrm{s})+\mathrm{X}_{2}

Multiple Choice Options

  • A All halogens
  • B Only Iodine
  • C Only Bromine
  • D Only Chlorine

Step-by-Step Verified Solution

The given reaction describes the formation of a copper(II) halide and the corresponding diatomic halogen molecule. Not all halogens will cause this reaction to occur.

This reaction is known to occur with iodine (I) because the formation of I2\mathrm{I}_{2} (a diatomic iodine molecule) is easier due to the relatively low bond energy of the I−I\mathrm{I}-\mathrm{I} bond.

On the other hand, the bond energies of Cl−Cl\mathrm{Cl}-\mathrm{Cl} and Br−Br\mathrm{Br}-\mathrm{Br} are higher, making it more difficult for these diatomic halogen molecules to form. Thus, these halogens would not typically cause this reaction to occur.

Therefore, the correct answer is:

Option B : Only Iodine.

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