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QJEEM23Ch863a: JEE Main 2023 Chemistry - Class 12 JEEM23Ch863a Solution: Following figure shows dependence of molar conductance of two…

Following figure shows dependence of molar conductance of two electrolytes on concentration. Λmo\Lambda \mathop m\limits^o is the limiting molar conductivity.

JEE Main 2023 (Online) 29th January Morning Shift Chemistry - Electrochemistry Question 64 English

The number of incorrect‾\mathrm{\underline {incorrect} } statement(s) from the following is ___________

(A) Λmo\Lambda \mathop m\limits^o for electrolyte A is obtained by extrapolation

(B) For electrolyte B, Λm\Lambda \mathop m\limits vs c\sqrt c graph is a straight line with intercept equal to Λmo\Lambda \mathop m\limits^o

(C) At infinite dilution, the value of degree of dissociation approaches zero for electrolyte B.

(D) Λmo\Lambda \mathop m\limits^o for any electrolyte A and B can be calculated using λ∘\lambda^\circ for individual ions

Step-by-Step Verified Solution

(A) Λm∘\Lambda_{\mathrm{m}}^{\circ} for 'A' cannot be obtained by extra polation.

(C) At infinite dilution, value of degree of dissociation approaches one.

∴A\therefore \mathrm{A} and C\mathrm{C} are incorrect

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