Verified Solution • 2025–26 Session moderate

QJEEM23Ch660c: JEE Main 2023 Chemistry - Class 12 JEEM23Ch660c Solution: Given below are two statements: One is labelled as Assertion A…

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R.

Assertion A: JEE Main 2023 (Online) 30th January Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 69 English 1 can be easily reduced using Zn−Hg/HCl\mathrm{Zn}-\mathrm{Hg} / \mathrm{HCl} to JEE Main 2023 (Online) 30th January Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 69 English 2

Reason R:Zn−Hg/HCl\mathrm{R}: \mathrm{Zn}-\mathrm{Hg} / \mathrm{HCl} is used to reduce carbonyl group to −CH2−-\mathrm{CH}_{2}- group.

In the light of the above statements, choose the correct answer from the options given below:

Multiple Choice Options

  • A Both A and R{ \text {Both } A \text { and }} \mathrm{R} are true and R\mathrm{R} is the correct explanation of A\mathrm{A}
  • B A\mathrm{A} is false but R\mathrm{R} is true
  • C A is true but R\mathrm{R} is false
  • D Both A\mathrm{A} and R\mathrm{R} are true but R\mathrm{R} is not the correct explanation of A\mathrm{A}

Step-by-Step Verified Solution

The carbonyl group of aldehyde or ketone gets reduced to alkane on treatment with Zn-Hg with HCl and the reaction is named as Clemmensen reduction.

But for hydroxyaldehyde or hydroxyketone, the alcoholic group gets converted to alkyl halide while carbonyl group gets reduced to alkane.

JEE Main 2023 (Online) 30th January Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 69 English Explanation

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