Verified Solution • 2025–26 Session moderate

QJEEM23Ch2137: JEE Main 2023 Chemistry - Class 12 JEEM23Ch2137 Solution: Iron oxide FeO, crystallises in a cubic lattice with a unit…

Iron oxide FeO, crystallises in a cubic lattice with a unit cell edge length of 5.0 Å. If density of the FeO\mathrm{FeO} in the crystal is 4.0 g cm−34.0 \mathrm{~g} \mathrm{~cm}^{-3} , then the number of FeO\mathrm{FeO} units present per unit cell is __________. (Nearest integer)

Given: Molar mass of Fe\mathrm{Fe} and O\mathrm{O} is 56 and 16 g mol−116 \mathrm{~g} \mathrm{~mol}^{-1} respectively. NA=6.0×1023 mol−1\mathrm{N}_{\mathrm{A}}=6.0 \times 10^{23} \mathrm{~mol}^{-1}

Step-by-Step Verified Solution

d=z×ma3

4=z×726×1023(5×10−8)3

4=z×726×125×10−1

=z≈4

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