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QJEEM23Ch0b10: JEE Main 2023 Chemistry - Class 12 JEEM23Ch0b10 Solution: The hybridization and magnetic behaviour of cobalt ion in [ Co…

The hybridization and magnetic behaviour of cobalt ion in [Co(NH3)6]3+ complex, respectively is :

Multiple Choice Options

  • A sp3d2 and paramagnetic
  • B sp3d2 and diamagnetic
  • C d2sp3 and diamagnetic
  • D d2sp3 and paramagnetic

Step-by-Step Verified Solution

[Co(NH3)6]3+\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+} is diamagnetic with d2sp3\mathrm{d}^{2} \mathrm{sp}^{3} hybridisation of Co+3\mathrm{Co}^{+3} .

This is because NH3\mathrm{NH}_{3} is a strong field ligand and forces electrons to pair up in a d6\mathrm{d}^{6} configuration.

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