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QJEEM22Chd5c1: JEE Main 2022 Chemistry - Class 11 JEEM22Chd5c1 Solution: The number of N atoms in 681 g of C 7 H 5 N 3 O 6 is x × 10 21…

The number of N atoms in 681 g of C7H5N3O6 is x × 1021. The value of x is (NA = 6.02 × 1023 mol−1) (Nearest Integer)

Step-by-Step Verified Solution

First, determine the molar mass of the compound C 7_7 H 5_5 N 3_3 O 6_6 :

Carbon (C): 12 g/mol, and there are 7 C atoms: 7×12=84 g/mol7 \times 12 = 84 \text{ g/mol}

Hydrogen (H): 1 g/mol, and there are 5 H atoms: 5×1=5 g/mol5 \times 1 = 5 \text{ g/mol}

Nitrogen (N): 14 g/mol, and there are 3 N atoms: 3×14=42 g/mol3 \times 14 = 42 \text{ g/mol}

Oxygen (O): 16 g/mol, and there are 6 O atoms: 6×16=96 g/mol6 \times 16 = 96 \text{ g/mol}

Calculate the total molar mass:

Molar mass of C7H5N3O6=84+5+42+96=227 g/mol\text{Molar mass of C}_7\text{H}_5\text{N}_3\text{O}_6 = 84 + 5 + 42 + 96 = 227 \text{ g/mol}

Calculate the number of moles of C 7_7 H 5_5 N 3_3 O 6_6 in 681 grams:

Moles of C7H5N3O6=681 g227 g/mol=3 moles\text{Moles of C}_7\text{H}_5\text{N}_3\text{O}_6 = \frac{681 \text{ g}}{227 \text{ g/mol}} = 3 \text{ moles}

Each molecule of C 7_7 H 5_5 N 3_3 O 6_6 contains 3 nitrogen atoms. Thus, in 3 moles, the total moles of nitrogen atoms is:

Moles of N atoms=3×3=9 moles\text{Moles of N atoms} = 3 \times 3 = 9 \text{ moles}

Using Avogadro's number, calculate the number of nitrogen atoms:

Number of N atoms=9 moles×6.02×1023 atoms/mole\text{Number of N atoms} = 9 \text{ moles} \times 6.02 \times 10^{23} \text{ atoms/mole}

=54.18×1023=5.418×1024 N atoms= 54.18 \times 10^{23} = 5.418 \times 10^{24} \text{ N atoms}

Convert this number to the form x×1021x \times 10^{21} :

5.418×1024=5418×10215.418 \times 10^{24} = 5418 \times 10^{21}

Thus, the value of xx is:

x=5418x = 5418

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