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QJEEM22Chba96: JEE Main 2022 Chemistry - Class 11 JEEM22Chba96 Solution: Given below are the quantum numbers for 4 electrons. A. n = 3 , …

Given below are the quantum numbers for 4 electrons.

A. n=3,l=2, m1=1, ms=+1/2

B. n=4,l=1, m1=0, ms=+1/2

C. n=4,l=2, m1=−2, ms=−1/2

D. n=3,l=1, m1=−1, ms=+1/2

The correct order of increasing energy is :

Multiple Choice Options

  • A D < B < A < C
  • B D < A < B < C
  • C B < D < A < C
  • D B < D < C < A

Step-by-Step Verified Solution

The order of increasing energy of electrons in an atom can generally be determined using the principal quantum number ( nn ) and the azimuthal quantum number ( ll ). The energy can be compared using the rule: the higher the (n+l)(n + l) value, the higher the energy. If two electrons have the same (n+l)(n + l) value, the electron with the higher nn value has the higher energy.

Analyze each electron's quantum numbers:

A. n=3, l=2⇒n+l=3+2=5

B. n=4, l=1⇒n+l=4+1=5

C. n=4, l=2⇒n+l=4+2=6

D. n=3, l=1⇒n+l=3+1=4

Comparing the values of (n+l)(n + l) and the principal quantum number nn :

D: n+l=4n+l = 4 , and n=3n=3 .

A and B: n+l=5n+l = 5 , but A has n=3n=3 while B has n=4n=4 . Therefore, A has a slightly lower energy than B.

C: n+l=6n+l = 6 .

Thus, the correct order of increasing energy is:

D<A<B<C

Therefore, Option B is correct.

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