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QJEEM22Ch9f4d: JEE Main 2022 Chemistry - Class 12 JEEM22Ch9f4d Solution: For the given reactions Sn 2+ + 2e − → Sn Sn 4+ + 4e − → Sn the …

For the given reactions

Sn2+ + 2e− → Sn

Sn4+ + 4e− → Sn

the electrode potentials are ; ESn2+/Sno=−0.140 V and ESn4+/Sno=+0.010 V. The magnitude of standard electrode potential for Sn4+/Sn2+ i.e. ESn4+/Sn2+o is _____________ × 10−2 V. (Nearest integer)

Step-by-Step Verified Solution

Sn⟶Sn2++2e−E10=0.140 V\mathrm{Sn} \longrightarrow \mathrm{Sn}^{2+}+2 \mathrm{e}^{-} \quad \mathrm{E}_{1}^{0}=0.140 \mathrm{~V}

Sn4++4e−⟶SnE20=0.010 V

Sn4++2e−⟶Sn2+Ecell 0EcellO=n2E2o+n1E10n=4(0.010)+2(0.140)2Ecell 0=0.16 V=16×10−2 V

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