Verified Solution • 2025–26 Session moderate

QJEEM22Ch9f1c: JEE Main 2022 Chemistry - Class 12 JEEM22Ch9f1c Solution: Given below are two statements : Statement I : According to…

Given below are two statements :

Statement I : According to Ellingham diagram, any metal oxide with higher ΔG∘ is more stable than the one with lower ΔG∘.

Statement II : The metal involved in the formation of oxide placed lower in the Ellingham diagram can reduce the oxide of a metal placed higher in the diagram.

In the light of the above statements, choose the most appropriate answer from the options given below :

Multiple Choice Options

  • A Both Statement I and Statement II are correct.
  • B Both Statement I and Statement II are incorrect.
  • C Statement I is correct but Statement II is incorrect.
  • D Statement I is incorrect but Statement II is correct.

Step-by-Step Verified Solution

Ellingham diagram is plot of ΔG vs T. The criterion for the feasibility of a thermal reduction is that at a given temperature Gibbs energy change of a reaction must be negative. The change in Gibbs energy, ΔG for any process at any specified temperature is given by the equation

ΔG = ΔH - TΔS

where ΔH = enthalpy change and ΔS = entropy change

According to the ellingham diagram, any metal oxide with higher ΔG° has a tendency of getting reduced by the metal whose metal oxide has lower value of ΔG°.

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