Verified Solution • 2025–26 Session moderate

QJEEM22Ch9797: JEE Main 2022 Chemistry - Class 11 JEEM22Ch9797 Solution: Which one of the following reactions indicates the reducing…

Which one of the following reactions indicates the reducing ability of hydrogen peroxide in basic medium?

Multiple Choice Options

  • A HOCl + H2O2 →\to H3O+ + Cl −- + O2
  • B PbS + 4H2O2 →\to PbSO4 + 4H2O
  • C 2MnO 4−_4^ - + 3H2O2 →\to 2MnO2 + 3O2 + 2H2O + 2OH −-
  • D Mn2+ + H2O2 →\to Mn4+ + 2OH −-

Step-by-Step Verified Solution

2MnO4−+7+3H2O2→2 \mathrm{Mn}\overset{+7}{\mathrm{O}_{4}^{-}}+3 \mathrm{H}_{2} \mathrm{O}_{2} \rightarrow

2MnO2+4+3O2+2H2O+2OH‾2 \mathrm{Mn}\overset{+4}{\mathrm{O}_{2}}+3 \mathrm{O}_{2}+2 \mathrm{H}_{2} \mathrm{O}+2 \mathrm{O} \overline{\mathrm{H}}

In basic medium MnO4−\mathrm{MnO}_{4}^{-} is reduced to MnO2\mathrm{MnO}_{2} , whereas in acidic medium it is reduced to Mn+2\mathrm{Mn}^{+2} .

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