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QJEEM22Ch92c0: JEE Main 2022 Chemistry - Class 11 JEEM22Ch92c0 Solution: Arrange the following carbocations in decreasing order of…

Arrange the following carbocations in decreasing order of stability.

JEE Main 2022 (Online) 24th June Evening Shift Chemistry - Basics of Organic Chemistry Question 117 English

Multiple Choice Options

  • A B > A > C
  • B A > B > C
  • C C > B > A
  • D C > A > B

Step-by-Step Verified Solution

The given carbocations are

JEE Main 2022 (Online) 24th June Evening Shift Chemistry - Basics of Organic Chemistry Question 117 English Explanation 1
Carbocation (A) is stabilised by hyperconjugation due to 4α4 \alpha hydrogen atoms. Carbocation (C) is also stabilised by hyperconjugation due to 4 a hydrogen atoms but destabilised by −1-1 effect of O-atom. Carbocation (B) is most stable as it is stabilised by resonance.

JEE Main 2022 (Online) 24th June Evening Shift Chemistry - Basics of Organic Chemistry Question 117 English Explanation 2
∴\therefore Correct decreasing order of stability is \text { B }>\text { A }>\text { C }

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