Verified Solution • 2025–26 Session moderate

QJEEM22Ch738d: JEE Main 2022 Chemistry - Class 11 JEEM22Ch738d Solution: 0.25 g of an organic compound containing chlorine gave 0.40 g…

0.25 g of an organic compound containing chlorine gave 0.40 g of silver chloride in Carius estimation. The percentage of chlorine present in the compound is ___________. [in nearest integer]

(Given : Molar mass of Ag is 108 g mol−1 and that of Cl is 35.5 g mol−1)

Step-by-Step Verified Solution

Given, weight of organic compound = 0.25 g

Moles of AgCl = 0.4M

Molecular mass of AgCl (M) = 143.5 gm

∴ Moles of AgCl = 0.4143.5

∴ Mass of Cl = 0.4143.5 × 35.5

Mass % of Cl in the organic compound

=35.5×0.4143.50.25×35.5

=39.58

≃40

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