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QJEEM22Ch6d5a: JEE Main 2022 Chemistry - Class 12 JEEM22Ch6d5a Solution: TLC analysis of a mixture having 3 components (A, B, C) using…

TLC analysis of a mixture having 3 components (A, B, C) using silica gel as the stationary phase gave following Rf values; for A = 0.72, B = 0.48, C = 0.20.

Regarding the above observations, which one of the following statements is not correct for column chromatography of the mixture?

Multiple Choice Options

  • A A is the most non-polar component
  • B C is the most soluble component in mobile phase
  • C A will be eluted first
  • D C is the most strongly absorbed component

Step-by-Step Verified Solution

The Rf\mathrm{R}_{f} (retardation factor) value is the ratio of the Solute's distance travelled to the Solvent's distance travelled.

Polar molecules will attract more toward adsorbent and cover smaller distance from the baseline. A has maximum Rf\mathrm{R}_{f} so it will less adsorbed on the adsorbent surface and travel faster and will be eluded first.

C\mathrm{C} has minimum Rf\mathrm{R}_{f} value. So it is more strongly adsobred and less soluble in mobile phase.

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