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QJEEM22Ch615d: JEE Main 2022 Chemistry - Class 11 JEEM22Ch615d Solution: On complete combustion 0.30 g of an organic compound gave 0.20…

On complete combustion 0.30 g of an organic compound gave 0.20 g of carbon dioxide and 0.10 g of water. The percentage of carbon in the given organic compound is _____________. (Nearest integer)

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CxHy+(x+y4)O2→x CO2+y2H2O{C_x}{H_y} + \left( {x + {y \over 4}} \right){O_2} \to x\,C{O_2} + {y \over 2}{H_2}O

Given organic compound CxHy= 0.3 gm

Produced carbon dioxide (CO2) = 0.2 gm

Produced water (H2O) = 0.1 gm

Moles of CO2 = 0.244{{0.2} \over {44}}

∴\therefore Moles of C atom = 0.244{{0.2} \over {44}}

∴\therefore Mass of C atom = 0.244{{0.2} \over {44}} ×\times 12 = 0.0545

Moles of H2O = 0.118{{0.1} \over {18}}

∴\therefore Moles of H atoms = 0.118{{0.1} \over {18}} ×\times 2

∴\therefore Mass of H atoms = 0.1×218{{0.1} \times2\over {18}} ×\times 1 = 0.0111

∴\therefore % of C atom = 0.05450.3{{0.0545} \over {0.3}} ×\times 100 = 18%

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