Verified Solution • 2025–26 Session moderate

QJEEM22Ch5b5f: JEE Main 2022 Chemistry - Class 11 JEEM22Ch5b5f Solution: Given below are two statements : one is labelled as Assertion…

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : The ionic radii of O2 −- and Mg2+ are same.

Reason (R) : Both O2 −- and Mg2+ are isoelectronic species.

In the light of the above statements, choose the correct answer from the options given below.

Multiple Choice Options

  • A Both (A) and (R) are true and (R) is the correct explanation of (A).
  • B Both (A) and (R) are true but (R) is not the correct explanation of (A).
  • C (A) is true but (R) is false.
  • D (A) is false but (R) is true.

Step-by-Step Verified Solution

Correct order of ionic radii:

O–2 > Mg+2

This is because among isoelectronic species, the size of anions are greater than the size of cations. Statement (II) is correct as both O–2 and Mg+2 are isoelectronic.

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