Verified Solution • 2025–26 Session moderate

QJEEM22Ch344e: JEE Main 2022 Chemistry - Class 12 JEEM22Ch344e Solution: Given below are two statements : one is labelled as Assertion…

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Experimental reaction of CH3Cl\mathrm{CH}_{3} \mathrm{Cl} with aniline and anhydrous AlCl3\mathrm{AlCl}_{3} does not give oo and pp -methylaniline.

Reason (R): The −NH2-\mathrm{NH}_{2} group of aniline becomes deactivating because of salt formation with anhydrous AlCl3\mathrm{AlCl}_{3} and hence yields mm -methyl aniline as the product.

In the light of the above statements, choose the most appropriate answer from the options given below :

Multiple Choice Options

  • A Both A and R are true and (R) is the correct explanation of (A).
  • B Both A and R are true but (R) is not the correct explanation of (A).
  • C (A) is true, but (R) is false.
  • D (A) is false, but (R) is true.

Step-by-Step Verified Solution

JEE Main 2022 (Online) 26th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 85 English Explanation

Aniline does not undergo Friedel Craft reaction because the reagent AlCl3 being electron deficient acts as a Lewis acid.

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