Verified Solution • 2025–26 Session moderate

QJEEM22Ch0f51: JEE Main 2022 Chemistry - Class 11 JEEM22Ch0f51 Solution: At 25 C and 1 atm pressure, the enthalpies of combustion are as …

At 25 ∘^\circ C and 1 atm pressure, the enthalpies of combustion are as given below :

Substance H2{H_2} C (graphite) C2H6(g){C_2}{H_6}(g)
ΔcHΘkJ mol−1{{{\Delta _c}{H^\Theta }} \over {kJ\,mo{l^{ - 1}}}} −286.0- 286.0 −394.0- 394.0 −1560.0- 1560.0

The enthalpy of formation of ethane is

Multiple Choice Options

  • A +54.0 kJ mol −- 1
  • B −- 68.0 kJ mol −- 1
  • C −- 86.0 kJ mol −- 1
  • D +97.0 kJ mol −- 1

Step-by-Step Verified Solution

2C2 \mathrm{C} (graphite) +3H2( g)→C2H6( g)+3 \mathrm{H}_{2}(\mathrm{~g}) \rightarrow \mathrm{C}_{2} \mathrm{H}_{6}(\mathrm{~g})

ΔHr=+1560+2(−394)+3(−286)\Delta \mathrm{H}_{\mathrm{r}}=+1560+2(-394)+3(-286)

=−86.0 kJ mol−1=-86.0 \mathrm{~kJ} \mathrm{~mol}^{-1}

Enthalpy of formation of C2H6(g) = –86.0 kJ mol–1

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