Verified Solution • 2025–26 Session moderate

QJEEM21Ph6953: JEE Main 2021 Physics - Class 11 JEEM21Ph6953 Solution: The work done by a gas molecule in an isolated system is given…

The work done by a gas molecule in an isolated system is

given by, W=αβ2e−x2αkTW = \alpha {\beta ^2}{e^{ - {{{x^2}} \over {\alpha kT}}}} , where x is the displacement, k is the Boltzmann constant and T is the temperature. α\alpha and β\beta are constants. Then the dimensions of β\beta will be :

Multiple Choice Options

  • A [M0LT0][{M^0}L{T^0}]
  • B [ML2T−2][M{L^2}{T^{ - 2}}]
  • C [MLT−2][ML{T^{ - 2}}]
  • D [M2LT2][{M^2}L{T^2}]

Step-by-Step Verified Solution

where, k is Boltzmann constant,

T is temperature and x is displacement.

We know that, x2αkT{{{x^2}} \over {\alpha kT}} is a dimensionless quantity.

∴\therefore [x2αkT]=[M0L0T0]⇒[α]=[x2][k][T]\left[ {{{{x^2}} \over {\alpha kT}}} \right] = [{M^0}{L^0}{T^0}] \Rightarrow [\alpha ] = {{[{x^2}]} \over {[k][T]}}

⇒[α]=[L2][k][T]\Rightarrow [\alpha ] = {{[{L^2}]} \over {[k][T]}} ..... (i)

Since, dimensions of k are

[k]=[M1L2T−2K−1][k] = [{M^1}{L^2}{T^{ - 2}}{K^{ - 1}}] ...... (ii)

Dimensions of temperature are

[T]=[K][T] = [K] ..... (iii)

Substituting Eqs. (ii) and (iii) in Eq. (i), we get

[α]=[L2][M1L2T−2K−1][K][\alpha ] = {{[{L^2}]} \over {[{M^1}{L^2}{T^{ - 2}}{K^{ - 1}}][K]}}

[α]=[M−1T2][\alpha ] = [{M^{ - 1}}{T^2}]

According to dimensional analysis,

[W]=[αβ2][W] = [\alpha {\beta ^2}]

⇒[β2]=[W][α]\Rightarrow [{\beta ^2}] = {{[W]} \over {[\alpha ]}}

⇒[β2]=M1L2T−2][M−1T2]=[M2L2T−4]\Rightarrow [{\beta ^2}] = {{{M^1}{L^2}{T^{ - 2}}]} \over {[{M^{ - 1}}{T^2}]}} = [{M^2}{L^2}{T^{ - 4}}]

⇒[β]=[MLT−2]\Rightarrow [\beta ] = [ML{T^{ - 2}}]

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