Verified Solution • 2025–26 Session moderate

QJEEM21Ph1b07: JEE Main 2021 Physics - Class 11 JEEM21Ph1b07 Solution: The temperature of 3.00 mol of an ideal diatomic gas is…

The temperature of 3.00 mol of an ideal diatomic gas is increased by 40.0 ∘^\circ C without changing the pressure of the gas. The molecules in the gas rotate but do not oscillate. If the ratio of change in internal energy of the gas to the amount of workdone by the gas is x10{x \over {10}} . Then the value of x (round off to the nearest integer) is ___________. (Given R = 8.31 J mol −- 1 K −- 1)

Step-by-Step Verified Solution

Given, the number of diatomic moles, n = 3 mol

The increase in temperature of the diatomic mole,

Δ\Delta T = 40 ∘^\circ C

Now, the degree of freedom

f = linear + rotational + no oscillation

f = 3 + 2 + 0 ⇒\Rightarrow f = 5

Change in internal energy,

Δ\Delta U = nCv Δ\Delta T .... (i)

where, Cv=f2R=52R{C_v} = {f \over 2}R = {5 \over 2}R

Substituting the value in Eq. (i), we get

ΔU=5R2nRΔT\Delta U = {{5R} \over 2}nR\Delta T

Now, work done by the gas for isobaric process,

W=pΔV=nRΔTW = p\Delta V = nR\Delta T

The ratio of the change in internal energy to the work done by the gas,

ΔUW=52nRΔTnRΔT{{\Delta U} \over W} = {{{5 \over 2}nR\Delta T} \over {nR\Delta T}}

=ΔUW=52= {{\Delta U} \over W} = {5 \over 2}

Multiply and divide the above equation with 5, we get

ΔUW=5×52×5=2510{{\Delta U} \over W} = {{5 \times 5} \over {2 \times 5}} = {{25} \over {10}}

Comparing with given equation, ΔUW=x10{{\Delta U} \over W} = {x \over {10}}

The value of the x = 25.

Related Learning Resources & Exam Preparation