Verified Solution • 2025–26 Session moderate

QJEEM21Chfa7d: JEE Main 2021 Chemistry - Class 12 JEEM21Chfa7d Solution: Given below are two statements : Statement I : o-Nitrophenol is …

Given below are two statements :

Statement I : o-Nitrophenol is steam volatile due to intramolecular hydrogen bonding.

Statement II : o-Nitrophenol has high melting due to hydrogen bonding.

In the light of the above statements, choose the most appropriate answer from the options given below :

Multiple Choice Options

  • A Both Statement I and Statement II are true
  • B Statement I is true but Statement II is false
  • C Statement I is false but Statement II is true
  • D Both Statement I and Statement II are false

Step-by-Step Verified Solution

JEE Main 2021 (Online) 26th February Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 104 English Explanation

So it is more volatile due to intramolecular H-bonding.

Melting point depends on packing efficiency not on H-bonding thus statement II is false.

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