Verified Solution • 2025–26 Session moderate

QJEEM21Chdacc: JEE Main 2021 Chemistry - Class 11 JEEM21Chdacc Solution: Match List - I with List - II. List I (Salt) List II (Flame…

Match List - I with List - II.

List I (Salt) List II (Flame colour wavelength)
(a) LiCl (i) 455.5 nm
(b) NaCl (ii) 670.8 nm
(c) RbCl (iii) 780.0 nm
(d) CsCl (iv) 589.2 nm


Choose the correct answer from the options given below :

Multiple Choice Options

  • A (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii)
  • B (a)-(iv), (b)-(ii), (c)-(iii), (d)-(i)
  • C (a)-(i), (b)-(iv), (c)-(ii), (d)-(iii)
  • D (a)-(ii), (b)-(iv), (c)-(iii), (d)-(i)

Step-by-Step Verified Solution

Alkali metal Colour (Flame) λ\lambda (nm)
Li Crimson red 670.8
Na Yellow 589.2
Rb Red, violet 780.0
Cs Blue 455.5

Alkali metals have very low value of ionisation energy as compared to other metals. So, alkali metals easily get excited and impart colour to flame.

Hence, Rb is most excited and having high value of wavelength in all alkali metals.

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