Verified Solution • 2025–26 Session moderate

QJEEM21Chd9c2: JEE Main 2021 Chemistry - Class 11 JEEM21Chd9c2 Solution: Given below are two statements. Statement I : In the titration…

Given below are two statements.

Statement I : In the titration between strong acid and weak base methyl orange is suitable as an indicator.

Statement II : For titration of acetic acid with NaOH phenolphthalein is not a suitable indicator.

In the light of the above statements, choose the most appropriate answer from the options given below :

Multiple Choice Options

  • A Statement I is false but Statement II is true
  • B Statement I is true but Statement II is false
  • C Both Statement I and Statement II are true
  • D Both Statement I and Statement II are false

Step-by-Step Verified Solution

Titration curve for strong acid and weak base initially a buffer of weak base and conjugate acid is :

JEE Main 2021 (Online) 26th August Morning Shift Chemistry - Ionic Equilibrium Question 53 English Explanation 1

Formed, thus pH falls slowly and after equivalence point, so the pH falls sharply so methyl orange, having pH range of 3.2 to 4.4 will weak as indicator. So, statement I is correct.

JEE Main 2021 (Online) 26th August Morning Shift Chemistry - Ionic Equilibrium Question 53 English Explanation 2

Titration curve for weak acid and strong base (NaOH)

Initially weak acid will form a buffer so pH increases slowly but after equivalence point. It rises sharply covering range of phenolphthalein so it will be suitable indicator so statement II is false.

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