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QJEEM21Chb987: JEE Main 2021 Chemistry - Class 11 JEEM21Chb987 Solution: Match List - I with List - II. List I Electronic configuration…

Match List - I with List - II.

List I
Electronic configuration
List II
ΔiH{\Delta _i}H in kJ mol−1mo{l^{ - 1}}
(a) 1s22s21{s^2}2{s^2} (i) 801
(b) 1s22s22p41{s^2}2{s^2}2{p^4} (ii) 899
(c) 1s22s22p31{s^2}2{s^2}2{p^3} (iii) 1314
(d) 1s22s22p11{s^2}2{s^2}2{p^1} (iv) 1402

Choose the most appropriate answer from the options given below :

Multiple Choice Options

  • A (a) →\to (i), (b) →\to (iii), (c) →\to (iv), (d) →\to (iii)
  • B (a) →\to (iv), (b) →\to (i), (c) →\to (ii), (d) →\to (iii)
  • C (a) →\to (ii), (b) →\to (iii), (c) →\to (iv), (d) →\to (i)
  • D (a) →\to (i), (b) →\to (iv), (c) →\to (iii), (d) →\to (ii)

Step-by-Step Verified Solution

(a) 1s2 2s2 →\to Be

(b) 1s2 2s2 2p4 →\to O

(c) 1s2 2s2 2p3 →\to N

(d) 1s2 2s2 2p1 →\to B

The ionization enthalpy order is

B < Be < O < N

Be has more IE compared to B due to extra stability & N has more IE compared to oxygen due to extra stability.

Hence, N →\to 1402 kJ/mol

O →\to 1314 kJ/mol

B →\to 801 kJ/mol

Be →\to 899 kJ/mol

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