Verified Solution • 2025–26 Session
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QJEEM21Chaa61: JEE Main 2021 Chemistry - Class 11 JEEM21Chaa61 Solution: For the reaction A (g) B (g) the value of the equilibrium…
For the reaction A(g) B(g) the value of the equilibrium constant at 300 K and 1 atm is equal to 100.0. The value of rG for the reaction at 300 K and 1 atm in J mol-1 is – xR, where x is _______. (Rounded off to the nearest integer)
[R = 8.31 J mol–1K-1 and ln 10 = 2.3)
[R = 8.31 J mol–1K-1 and ln 10 = 2.3)
Step-by-Step Verified Solution
For a reaction, A(g) B(g)
Given, Kp (equilibrium constant) = 100
Temperature = 300 K
Pressure = 1 atm
Formula used, G = RT ln Kp .... (i)
Here, G = standard Gibb's free energy
R = gas constant = 8.31 J mol 1 K 1
Put value in Eq. (i), we get
G = R (300) ln 100
G = R (300) (2) ln (10)
ln (10) = 2.3
G = R(300) (2) (2.3)
G = 1380 R
Hence, G = xR
x = 1380
Given, Kp (equilibrium constant) = 100
Temperature = 300 K
Pressure = 1 atm
Formula used, G = RT ln Kp .... (i)
Here, G = standard Gibb's free energy
R = gas constant = 8.31 J mol 1 K 1
Put value in Eq. (i), we get
G = R (300) ln 100
G = R (300) (2) ln (10)
ln (10) = 2.3
G = R(300) (2) (2.3)
G = 1380 R
Hence, G = xR
x = 1380