Verified Solution • 2025–26 Session moderate

QJEEM21Ch695d: JEE Main 2021 Chemistry - Class 11 JEEM21Ch695d Solution: Given below are two statements : One is labelled as Assertion A …

Given below are two statements : One is labelled as Assertion A and other is labelled as Reason R.

Assertion A : The dihedral angles in H2O2 in gaseous phase is 90.2 ∘^\circ and in solid phase is 111.5 ∘^\circ .

Reason R : The change in dihedral angle in solid and gaseous phase is due to the difference in the intermolecular forces.

Choose the most appropriate answer from the options given below for A and R.

Multiple Choice Options

  • A A is correct but R is not correct.
  • B Both A and R are correct but R is not the correct explanation of A.
  • C Both A and R are correct and R is the correct explanation of A.
  • D A is not correct but R is correct.

Step-by-Step Verified Solution

JEE Main 2021 (Online) 20th July Morning Shift Chemistry - Hydrogen Question 44 English Explanation

(a) H2O2 structure in gas phase, dihedral angle is 111.5°.

(b) H2O2 structure in solid phase at 110K, dihedral angle is 90.2°

Hence given statement (A) is not correct.

But statement (B) is correct.

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