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QJEEM21Ch64aa: JEE Main 2021 Chemistry - Class 11 JEEM21Ch64aa Solution: When 10 mL of an aqueous solution of KMnO 4 was titrated in…
When 10 mL of an aqueous solution of KMnO4 was titrated in acidic medium, equal volume of 0.1 M of an aqueous solution of ferrous sulphate was required for complete discharge of colour. The strength of KMnO4 in grams per litre is __________ 10 2. (Nearest integer)
[Atomic mass of K = 39, Mn = 55, O = 16]
[Atomic mass of K = 39, Mn = 55, O = 16]
Step-by-Step Verified Solution
Let molarity of KMnO4 = x

(Equivalents of KMnO4 reacted) = (Equivalents of FeSO4 reacted)
(5 x 10 ml) = 1 0.1 10 ml
x = 0.02 M
Molar mass of KMnO4 = 158 gm/mol
Strength = (x 158) = 3.16 g/l

(Equivalents of KMnO4 reacted) = (Equivalents of FeSO4 reacted)
Molar mass of KMnO4 = 158 gm/mol