Verified Solution • 2025–26 Session moderate

QJEEM21Ch52d5: JEE Main 2021 Chemistry - Class 11 JEEM21Ch52d5 Solution: For the reaction, 2NO 2 (g) N 2 O 4 (g), when S = 176.0 JK 1…

For the reaction, 2NO2(g) ⇌\rightleftharpoons N2O4(g), when Δ\Delta S = −- 176.0 JK −- 1 and Δ\Delta H = −- 57.8 kJ mol −- 1, the magnitude of Δ\Delta G at 298 K for the reaction is ___________ kJ mol −- 1. (Nearest integer)

Step-by-Step Verified Solution

Given, Δ\Delta H = −- 57.8 kJ mol −- 1

Δ\Delta S = −- 176 JK −- 1 mol −- 1

T = 298 K

Using Gibb's free energy relation

Δ\Delta G = Δ\Delta H −- T Δ\Delta S

where, Δ\Delta G = change in Gibb's free energy

Δ\Delta H = change in enthalpy

T = temperature

Δ\Delta S = change in entropy

Δ\Delta G = 57.8 kJ/mol −- [298 K ×\times ( −- 176 Jk −- 1 mol −- 1)]

= 57.8 kJ/mol −- (298×−1761000kJ)\left( {298 \times {{ - 176} \over {1000}}kJ} \right) [ ∴\therefore 1 kJ = 1000 J]

= −- 5.352 kJ/mol

| Δ\Delta G | = 5.352

Hence, answer is 5.

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