Verified Solution • 2025–26 Session moderate

QJEEM21Ch098c: JEE Main 2021 Chemistry - Class 12 JEEM21Ch098c Solution: Given below are two statements : Statement I : CeO 2 can be…

Given below are two statements :

Statement I : CeO2 can be used for oxidation of aldehydes and ketones.

Statement II : Aqueous solution of EuSO4 is a strong reducing agent.

In the light of the above statements, choose the correct answer from the options given below :

Multiple Choice Options

  • A Statement I is true but Statement II is false.
  • B Statement I is false but Statement II is true
  • C Both Statement I and Statement II are false
  • D Both Statement I and Statement II are true

Step-by-Step Verified Solution

The +3 oxidation state of lanthanide is most stable and therefore lanthanide in +4 oxidation state has strong tendence to gain e– and converted into +3 and therefore act as strong oxidizing agent. eg Ce+4
And therefore CeO2 is used to oxidized alcohol aldehyde and ketones.

Lanthanide in +2 oxidation state has strong tendency to loss e– and converted into +3 oxidation state therefore act as strong reducing agent.

∴\therefore EuSO4 act as a strong reducing agent.

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