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QJEEM20Ph7a3d: JEE Main 2020 Physics - Class 12 JEEM20Ph7a3d Solution: In the line spectra of hydrogen atoms, difference between the…

In the line spectra of hydrogen atoms, difference between the largest and the shortest wavelengths of the Lyman series is 304 A0\mathop A\limits^0 . The corresponding difference for the Paschan series in A0\mathop A\limits^0 is : ___________.

Step-by-Step Verified Solution

For Lyman series :

Shortest wavelength,

λ\lambda s = R.12(112−1∞2)R{.1^2}\left( {{1 \over {{1^2}}} - {1 \over {{\infty ^2}}}} \right)

longest wavelength,

λ\lambda l = R.12(112−122)R{.1^2}\left( {{1 \over {{1^2}}} - {1 \over {{2^2}}}} \right)

Given, λ\lambda l - λ\lambda s = 304 A0\mathop A\limits^0

∴\therefore R.12(112−122)R{.1^2}\left( {{1 \over {{1^2}}} - {1 \over {{2^2}}}} \right) - R.12(112−1∞2)R{.1^2}\left( {{1 \over {{1^2}}} - {1 \over {{\infty ^2}}}} \right) = 304

⇒\Rightarrow 1R{1 \over R} = 912 A0\mathop A\limits^0

For Paschen series :

Shortest wavelength,

λ\lambda s = R.12(132−1∞2)R{.1^2}\left( {{1 \over {{3^2}}} - {1 \over {{\infty ^2}}}} \right) = R9{R \over 9}

longest wavelength,

λ\lambda l = R.12(132−142)R{.1^2}\left( {{1 \over {{3^2}}} - {1 \over {{4^2}}}} \right) = 7R144{{7R} \over {144}}

∴\therefore λ\lambda l - λ\lambda s

= 1447R−9R{{144} \over {7R}} - {9 \over R}

= (1447−9)1R\left( {{{144} \over 7} - 9} \right){1 \over R}

= (1447−9)×912\left( {{{144} \over 7} - 9} \right) \times 912 = 10553 A0\mathop A\limits^0

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