Verified Solution • 2025–26 Session moderate

QJEEM20Chb3ac: JEE Main 2020 Chemistry - Class 12 JEEM20Chb3ac Solution: Henry’s constant (in kbar) for four gases α , β , γ and δ in…

Henry’s constant (in kbar) for four gases α, β, γ and δ in water at 298 K is given below :

α β γ δ
KH 50 2 2 × 10-5 0.5

(density of water = 103 kg m-3 at 298 K)
This table implies that :

Multiple Choice Options

  • A solubility of γ at 308 K is lower than at 298 K
  • B The pressure of a 55.5 molal solution of δ is 250 bar
  • C α has the highest solubility in water at a given pressure
  • D The pressure of a 55.5 molal solution of γ is 1 bar

Step-by-Step Verified Solution

(1) On increasing temperature solubility of gases decreases.

(2) 55.5 molal solution of γ = 55.5 mol of

Pγ = KHXγ

= 2 × 10-5 × 55.555.5+100018

= 10–5 K bar

= 10–2 bar

(3) Pδ = KHXδ

= 0.5 × 55.555.5+100018

= 250 bar

(4) With temperature, the value of KH (Henry’s constant) increases and solubility of gas in liquid decreases.

Related Learning Resources & Exam Preparation