Verified Solution • 2025–26 Session moderate

QJEEM20Ch9ce5: JEE Main 2020 Chemistry - Class 12 JEEM20Ch9ce5 Solution: The pair in which both the species have the same magnetic…

The pair in which both the species have the same magnetic moment (spin only) is :

Multiple Choice Options

  • A [Cr(H2O)6]2+ and [CoCl4]2–
  • B [Co(OH)4]2– and [Fe(NH3)6]2+
  • C [Mn(H2O)6]2+ and [Cr(H2O)]2+
  • D [Cr(H2O)6]2+ and [Fe(H2O)6]2+

Step-by-Step Verified Solution

Species with same number of unpaired electrons have equal magnetic moment.

Complex Ligand Ligand Type Number of unpaired electrons
[Mn(H2O)6]2+ H2O Weak Field Ligand 5
[Cr(H2O)]2+ H2O Weak Field Ligand 4
[CoCl4]2– Cl Weak Field Ligand 3
[Fe(H2O)6]2+ H2O Weak Field Ligand 4
[Co(OH)4]2– OH Weak Field Ligand 3
[Fe(NH3)6]2+ NH3 Weak Field Ligand 4

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