Verified Solution • 2025–26 Session moderate

QJEEM20Ch5826: JEE Main 2020 Chemistry - Class 12 JEEM20Ch5826 Solution: 250 mL of a waste solution obtained from the workshop of a…

250 mL of a waste solution obtained from the workshop of a goldsmith contains 0.1 M AgNO3 and 0.1 M AuCl. The solution was electrolyzed at 2V by passing a current of 1A for 15 minutes. The metal/metals electrodeposited will be

[ EAg+/Ag0E_{A{g^ + }/Ag}^0 = 0.80 V, EAu+/Au0E_{A{u^ + }/Au}^0 = 1.69 V ]

Multiple Choice Options

  • A Silver and gold in equal mass proportion
  • B Silver and gold in proportion to their atomic weights
  • C Only gold
  • D Only silver

Step-by-Step Verified Solution

Millimoles of Au+ = 0.1 × 250 = 25

Mole of Au+ = 251000{{25} \over {1000}} = 140{1 \over {40}}

Charge passed = I × t = 1 × 15 × 60 = 900 C

moles of e– passed = 90096500{{900} \over {96500}} = 9965{9 \over {965}}

Only gold will be deposited as quantity of charge passed is less than the amount of Au+ present.

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