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QJEEM20Ch5074: JEE Main 2020 Chemistry - Class 11 JEEM20Ch5074 Solution: The first and second ionisation enthalpies of a metal are 496…
The first and second ionisation enthalpies of a metal are 496 and 4560 kJ mol–1, respectively. How many moles of HCl and H2SO4, respectively, will be needed to react completely with 1 mole of the metal hydroxide ?
Multiple Choice Options
- A 1 and 2
- B 1 and 0.5
- C 1 and 1
- D 2 and 0.5
Step-by-Step Verified Solution
First ionization enthalpies = 496 kJ/mole
Second ionization enthalpies = 4560 kJ/mol
According to the given information, the difference between first and second ionization enthalpy is very high so Metal belong to 1st group i.e. Monovalent cation.
Metal hydroxide will be of type, MOH.
MOH + HCl MCl + H2O
MOH + H2SO4 M2SO4 + H2O
So one mole of HCl required to react with one mole MOH.
And mole of H2SO4 required to react with one mole MOH.
Second ionization enthalpies = 4560 kJ/mol
According to the given information, the difference between first and second ionization enthalpy is very high so Metal belong to 1st group i.e. Monovalent cation.
Metal hydroxide will be of type, MOH.
MOH + HCl
MOH +
So one mole of HCl required to react with one mole MOH.
And