Verified Solution • 2025–26 Session moderate

QJEEM20Ch1466: JEE Main 2020 Chemistry - Class 12 JEEM20Ch1466 Solution: For the given cell : Cu(s)

For the given cell :

Cu(s) | Cu2+(C1M) || Cu2+(C2M) | Cu(s)

change in Gibbs energy (ΔG) is negative, if :

Multiple Choice Options

  • A C2 = 2C1
  • B C2 = C12
  • C C1 = 2C2
  • D C1 = C2

Step-by-Step Verified Solution

Given ΔG < 0

∴ -nFEcell < 0

⇒ Ecell > 0

We know, Ecell = Ecell0 - RT2Fln⁡(C1C2)

= 0 - RT2Fln⁡(C1C2)

∴ - RT2Fln⁡(C1C2) > 0

⇒ ln⁡(C1C2) < 0

⇒ C1 < C2

By checking option, we can see

C2 = 2C1 satisfy the condition C1 < C2.

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