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QJEEM19Ph79fe: JEE Main 2019 Physics - Class 11 JEEM19Ph79fe Solution: A 25 × 10 –3 m 3 volume cylinder is filled with 1 mol of O 2…

A 25 × 10–3 m3 volume cylinder is filled with 1 mol of O2 gas at room temperature (300K). The molecular diameter of O2, and its root mean square speed, are found to be 0.3 nm, and 200 m/s, respectively. What is the average collision rate (per second) for an O2 molecule ?

Multiple Choice Options

  • A ~1013
  • B ~1012
  • C ~1011
  • D ~1010

Step-by-Step Verified Solution

V = 25 × 10–3 m3, N = 1 mole of O2
T = 300 K
Vrms = 200 m/s

∵λ=12Nπr2\because \lambda = {1 \over {\sqrt 2 N\pi {r^2}}}

Average time {1 \over \tau } = {{ < V > } \over \lambda } = 200\,.N\pi {r^2}.\sqrt 2

=2×200×6.023×102325×10−3.π×10−18×0.09= {{\sqrt 2 \times 200 \times 6.023 \times {{10}^{23}}} \over {25 \times {{10}^{ - 3}}}}.\pi \times {10^{ - 18}} \times 0.09

Average no. of collision ≈1010\approx {10^{10}}

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