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QJEEM19Chf098: JEE Main 2019 Chemistry - Class 12 JEEM19Chf098 Solution: 10 mL of 1mM surfactant solution forms a monolayer covering…

10 mL of 1mM surfactant solution forms a monolayer covering 0.24 cm2 on a polar substrate. If the polar head is approximated as cube, what is its edge length?

Multiple Choice Options

  • A 1.0 pm
  • B 2.0 nm
  • C 0.1 nm
  • D 2.0 pm

Step-by-Step Verified Solution

No of moles formed = 10-3 ×\times 101000{{10} \over {1000}} = 10-5

∴\therefore No of molecules formed = 10-5 ×\times NA

In unimolecular layer formation each cube occupy an area = a2

∴\therefore Total area occupied = 10-5 ×\times NA ×\times a2

According to the question,

10-5 ×\times NA ×\times a2 = 0.24

⇒\Rightarrow 10-5 ×\times 6 ×\times 1023 ×\times a2 = 0.24

⇒\Rightarrow a2 = 4 ×\times 10-20

⇒\Rightarrow a = 2 ×\times 10-10 cm = 2 pm

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