Verified Solution • 2025–26 Session
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QJEEM19Cheadf: JEE Main 2019 Chemistry - Class 12 JEEM19Cheadf Solution: Consider the hydrated ions of Ti 2+ , V 2+ , Ti 3+ , and Sc 3+…
Consider the hydrated ions of Ti2+, V2+, Ti3+, and Sc3+. The correct order of their spin-only magnetic moments is :
Multiple Choice Options
- A Sc3+ < Ti3+ < V2+ < Ti2+
- B Sc3+ < Ti3+ < Ti2+ < V2+
- C Ti3+ < Ti2+ < Sc3+ < V2+
- D V2+ < Ti2+ < Ti3+ < Sc3+
Step-by-Step Verified Solution
As we know that
where n = no. of unpaired electrons i.e. greater the no. of unpaired electron more will be the spin-only magnetic moments.
. Electronic configuration of the given transition metal ions are
Sc3+ (Z = 21) = 1s22s22p63s23p6
n = 0
Ti2+ (Z = 22) = 1s22s22p63s23p63d2
n = 2
Ti3+ (Z = 22) = 1s22s22p63s23p63d1
n = 1
V2+ (Z = 23) = 1s22s22p63s23p63d3
n = 3
So the correct increasing order of magnetic moment is
Sc3+ < Ti3+ < Ti2+ < V2+
. Electronic configuration of the given transition metal ions are
Sc3+ (Z = 21) = 1s22s22p63s23p6
Ti2+ (Z = 22) = 1s22s22p63s23p63d2
Ti3+ (Z = 22) = 1s22s22p63s23p63d1
V2+ (Z = 23) = 1s22s22p63s23p63d3
So the correct increasing order of magnetic moment is
Sc3+ < Ti3+ < Ti2+ < V2+