Verified Solution • 2025–26 Session moderate

QJEEM19Cheadf: JEE Main 2019 Chemistry - Class 12 JEEM19Cheadf Solution: Consider the hydrated ions of Ti 2+ , V 2+ , Ti 3+ , and Sc 3+…

Consider the hydrated ions of Ti2+, V2+, Ti3+, and Sc3+. The correct order of their spin-only magnetic moments is :

Multiple Choice Options

  • A Sc3+ < Ti3+ < V2+ < Ti2+
  • B Sc3+ < Ti3+ < Ti2+ < V2+
  • C Ti3+ < Ti2+ < Sc3+ < V2+
  • D V2+ < Ti2+ < Ti3+ < Sc3+

Step-by-Step Verified Solution

As we know that

μ=n(n+2) where n = no. of unpaired electrons i.e. greater the no. of unpaired electron more will be the spin-only magnetic moments.

. Electronic configuration of the given transition metal ions are

Sc3+ (Z = 21) = 1s22s22p63s23p6

∴ n = 0

Ti2+ (Z = 22) = 1s22s22p63s23p63d2

∴ n = 2

Ti3+ (Z = 22) = 1s22s22p63s23p63d1

∴ n = 1

V2+ (Z = 23) = 1s22s22p63s23p63d3

∴ n = 3

So the correct increasing order of magnetic moment is

Sc3+ < Ti3+ < Ti2+ < V2+

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