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QJEEM19Chd196: JEE Main 2019 Chemistry - Class 12 JEEM19Chd196 Solution: The complex ion that will lose its crystal field stabilization…

The complex ion that will lose its crystal field stabilization energy upon oxidation of its metal to +3 state is : JEE Main 2019 (Online) 12th April Morning Slot Chemistry - Coordination Compounds Question 219 English

Multiple Choice Options

  • A [Fe(phen)3]2+
  • B [Zn(phen)3]2+
  • C [Co(phen)3]2+
  • D [Ni(phen)3]2+

Step-by-Step Verified Solution

[Fe(phen)3]2+ →\to [Fe(phen)3]3+

Here for Fe+2(3d6) :

CFSE = (-0.4 ×\times 4 + 0.6 ×\times 2) Δ\Delta 0

           = -0.4 Δ\Delta 0

for Fe+3(3d5) :

CFSE = (-0.4 ×\times 3 + 0.6 ×\times 2) Δ\Delta 0

           = 0

Here crystal field stabilization energy(CFSE) decreses.

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