Verified Solution • 2025–26 Session
moderate
QJEEM19Chae6a: JEE Main 2019 Chemistry - Class 12 JEEM19Chae6a Solution: Given CO 3+ + e – CO 2 + ; E o = + 1.81 V Pb 4+ + 2e – Pb 2 + ; …
Given
CO3+ + e– CO2+ ; Eo = + 1.81 V
Pb4+ + 2e– Pb2+ ; Eo = + 1.67 V
Ce4+ + e– Ce3+ ; Eo = + 1.61 V
Bi3+ + 3e– Bi ; Eo = + 0.20 V
Oxidizing power of the species will increase in the order :
CO3+ + e– CO2+ ; Eo = + 1.81 V
Pb4+ + 2e– Pb2+ ; Eo = + 1.67 V
Ce4+ + e– Ce3+ ; Eo = + 1.61 V
Bi3+ + 3e– Bi ; Eo = + 0.20 V
Oxidizing power of the species will increase in the order :
Multiple Choice Options
- A Co3+ < Ce4+ < Bi3+ < Pb4+
- B Co3+ < Pb4+ < Ce4+ < Bi3+
- C Ce4+ < Pb4+ < Bi3+ < Co3+
- D Bi3+ < Ce4+ < Pb4+ < Co3+
Step-by-Step Verified Solution
Higher the value of Standard reduction potential of metal ion electrode, the more strong oxidizing agent is that metal ion electrode and have greater oxidising power.
So, Bi3+ < Ce4+ < Pb4+ < Co3+
So, Bi3+ < Ce4+ < Pb4+ < Co3+