Verified Solution • 2025–26 Session moderate

QJEEM19Chae6a: JEE Main 2019 Chemistry - Class 12 JEEM19Chae6a Solution: Given CO 3+ + e – CO 2 + ; E o = + 1.81 V Pb 4+ + 2e – Pb 2 + ; …

Given

CO3+ + e– →\to CO2+ ; Eo = + 1.81 V

Pb4+ + 2e– →\to Pb2+ ; Eo = + 1.67 V

Ce4+ + e– →\to Ce3+ ; Eo = + 1.61 V

Bi3+ + 3e– →\to Bi ; Eo = + 0.20 V

Oxidizing power of the species will increase in the order :

Multiple Choice Options

  • A Co3+ < Ce4+ < Bi3+ < Pb4+
  • B Co3+ < Pb4+ < Ce4+ < Bi3+
  • C Ce4+ < Pb4+ < Bi3+ < Co3+
  • D Bi3+ < Ce4+ < Pb4+ < Co3+

Step-by-Step Verified Solution

Higher the value of Standard reduction potential of metal ion electrode, the more strong oxidizing agent is that metal ion electrode and have greater oxidising power.

So, Bi3+ < Ce4+ < Pb4+ < Co3+

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