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QJEEM19Ch9775: JEE Main 2019 Chemistry - Class 11 JEEM19Ch9775 Solution: A 10 mg effervescent tablet containing sodium bicarbonate and…

A 10 mg effervescent tablet containing sodium bicarbonate and oxalic acid releases 0.25 ml of CO2 at T = 298.15 K and p = 1 bar. If molar volume of CO2 is 25.0 L under such condition, what is the percentage of sodium bicarbonate in each tablet ?
[Molar mass of NaHCO3 = 84 g mol–1]

Multiple Choice Options

  • A 33.6
  • B 0.84
  • C 8.4
  • D 16.8

Step-by-Step Verified Solution

2NaHCO3 + (COOH)2 → (COONa)2 + 2H2O + 2CO2

∴ 1 mole of CO2 is produced by 1 mole of NaHCO3.

Given, volume of CO2 produced = 0.25 ml

25 L of CO2 contains 1 mol

∴ 0.25 ml of CO2 contains = 125×103×0.25 moles

= 10-5 moles

∴ Moles of NaHCO3 = 10-5 moles

Mass of NaHCO3 = 10-5 × 84 g

∴ % of NaHCO3 in a tablet

= 84×10−510×10−3×100 = 8.4 %

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