Verified Solution • 2025–26 Session
moderate
QJEEM19Ch2a04: JEE Main 2019 Chemistry - Class 12 JEEM19Ch2a04 Solution: Increasing rate of S N 1 reaction in the following compounds is :
Increasing rate of SN1 reaction in the following compounds is : 

Multiple Choice Options
- A (B) < (A) < (D) < (C)
- B (A) < (B) < (C) < (D)
- C (A) < (B) < (D) < (C)
- D (B) < (A) < (C) < (D)
Step-by-Step Verified Solution
The rate of SN1 is decided by the stability of carbocation which is formed when leaving group I(Iodine) leave from the compound. 
Carbocation (D) is most stable due to +R effect of CH3O group.
Carbocation (C) is stabilised by +I and +H effect of CH3 group.
Carbocation (B) is least stable due to –I effect of MeO group.

Carbocation (D) is most stable due to +R effect of CH3O group.
Carbocation (C) is stabilised by +I and +H effect of CH3 group.
Carbocation (B) is least stable due to –I effect of MeO group.