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QJEEM18Ph48bf: JEE Main 2018 Physics - Class 12 JEEM18Ph48bf Solution: The de-Broglie wavelength ( B ) associated with the electron…

The de-Broglie wavelength ( λ\lambda B) associated with the electron orbiting in the second excited state of hydrogen atom is related to that in the ground state ( λ\lambda G) by :

Multiple Choice Options

  • A λ\lambda B = 2 λ\lambda G
  • B λ\lambda B = 3 λ\lambda G
  • C λ\lambda B = λ\lambda G/2
  • D λ\lambda B = λ\lambda G/3

Step-by-Step Verified Solution

We know that, λ=hmv\lambda = {h \over {mv}}

From third Bohr's postulate, we have

mvr=nh2πmvr = n{h \over {2\pi }}

hmv=2πrn⇒λ=2πrn{h \over {mv}} = {{2\pi r} \over n} \Rightarrow \lambda = {{2\pi r} \over n}

Since, r=a0n2Zr = {a_0}{{{n^2}} \over Z} , where a0 is radius of Bohr's orbit having value (0.53) 12 Ao\mathop A\limits^o = 0.53 Ao\mathop A\limits^o , therefore,

λ=2πa0n2n . Z=2πa0Z . n\lambda = {{2\pi {a_0}{n^2}} \over {n\,.\,Z}} = {{2\pi {a_0}} \over Z}\,.\,n

For Hydrogen Z = 1. Therefore,

λG=2πa0×11=2πa0{\lambda _G} = {{2\pi {a_0} \times 1} \over 1} = 2\pi {a_0} and λB=2πa0×31=6πa0{\lambda _B} = {{2\pi {a_0} \times 3} \over 1} = 6\pi {a_0}

Then, λB=3λG{\lambda _B} = 3{\lambda _G}

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