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QJEEM18Ph1a1a: JEE Main 2018 Physics - Class 12 JEEM18Ph1a1a Solution: If the series limit frequency of the Lyman series is , then the …

If the series limit frequency of the Lyman series is νL{\nu _L} , then the series limit frequency of the Pfund series is:

Multiple Choice Options

  • A νL/25{\nu _L}/25
  • B 25νL25{\nu _L}
  • C 16νL16{\nu _L}
  • D νL/16{\nu _L}/16

Step-by-Step Verified Solution

Note :

(1)   In Lyman Series, transition happens in n = 1 state
from n = 2, 3, . . . . . ∝\propto

(2)   In Balmer Series, transition happens in n = 2 state
from n = 3, 4, . . . . . ∝\propto

(3)   In Paschen Series, transition happens in n = 3 state
from n = 4, 5, . . . . . ∝\propto

(4)   In Bracktt Series, transition happens in n = 4 state
from n = 5, 6 . . . . . . ∝\propto

(5)   In Pfund Series, transition happens in n = 5 state
from n = 6, 7, . . . . ∝\propto

We know,

1λ{1 \over \lambda }   =  RZ2 (1n12−1n22)\left( {{1 \over {n_1^2}} - {1 \over {n_2^2}}} \right)

Series limit means transition happens

from n = ∝\propto to n = 1, for Lyman Series.

In series limit for Lyman series,

1λL{1 \over {{\lambda _L}}} = RZ2 (112−1∝)\left( {{1 \over {{1^2}}} - {1 \over \propto }} \right)

⇒\Rightarrow    \,\,\, 1λL{1 \over {{\lambda _L}}} = RZ2

We know,

E = hcλ{{hc} \over \lambda } = h γ\gamma

⇒\Rightarrow    \,\,\, γ\gamma = cλ{c \over \lambda }

So, frequency in Lyman Series,

γ\gamma L =  cλL{c \over {{\lambda _L}}}   = c ×\times RZ2

In Pfund series,

n2 = ∝\propto  and  n1 = 5

∴   \therefore\,\,\, 1λP{1 \over {{\lambda _P}}}  = RZ2 (152−1∝2)\left( {{1 \over {{5^2}}} - {1 \over {{ \propto ^2}}}} \right)

⇒\Rightarrow    \,\,\, 1λP{1 \over {{\lambda _P}}} = RZ225{{R{Z^2}} \over {25}}

∴   \therefore\,\,\, γP{\gamma _P}   =   cλP{c \over {{\lambda _P}}} = c ×\times RZ225{{R{Z^2}} \over {25}}

∴   \therefore\,\,\, γ\gamma P = cRZ225{{cRZ{}^2} \over {25}} = γL25{{{\gamma _L}} \over {25}}    [as   γ\gamma L = cRZ2]

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