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QJEEM16Chb002: JEE Main 2016 Chemistry - Class 11 JEEM16Chb002 Solution: Identify the incorrect statement regarding heavy water:

Identify the incorrect statement regarding heavy water:

Multiple Choice Options

  • A It is used as a coolant in nuclear reactors.
  • B It reacts with SO3 to form deuterated sulphuric acid (D2SO4).
  • C It reacts with Al4C3 to produce CD4 and Al(OD)3 .
  • D It reacts with CaC2 to produce C2D2 and Ca(OD)2 .

Step-by-Step Verified Solution

Incorrect Statement: It is used as a coolant in nuclear reactors.


Chemical Equations:

  • Al4C3+12D2O→4Al(OD)3+3CD4Al_4C_3 + 12D_2O \rightarrow 4Al(OD)_3 + 3CD_4
  • CaC2+2D2O→Ca(OD)2+C2D2CaC_2 + 2D_2O \rightarrow Ca(OD)_2 + C_2D_2
  • SO3+D2O→D2SO4SO_3 + D_2O \rightarrow D_2SO_4

Reasoning:

The chemical equations provided in the other options are standard and scientifically accurate. In the context of nuclear reactors, we can distinguish between the primary role of heavy water (as a moderator to slow down neutrons) and the role of ordinary water (the standard coolant). Therefore, this statement is considered the most appropriate answer here, and the incorrect one among the given choices.

Note: While D2OD_2O is used as a coolant in certain specific reactor designs, it is primarily categorized as a moderator and this is the most appropriate answer here..

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