Verified Solution • 2025–26 Session moderate

QJEEM16Ch75c5: JEE Main 2016 Chemistry - Class 11 JEEM16Ch75c5 Solution: The group of molecules having identical shape is :

The group of molecules having identical shape is :

Multiple Choice Options

  • A SF4 , XeF4 , CCl4
  • B ClF3 , XeOF2 , XeF 3+_3^ +
  • C BF3 , PCl3 , XeO3
  • D PCl5 , IF5 , XeO2F2

Step-by-Step Verified Solution

H = 12{1 \over 2} [VE + MA – c + a]

ClF3 , H = 12{1 \over 2} (7 + 3 – 0 + 0) = 5 (sp3d)

XeOF2 , H = 12{1 \over 2} (8 + 2 – 0 + 0) = 5 (sp3d)

XeF3+ , H = 12{1 \over 2} (8 + 3 – 1 + 0 ) = 5 (sp3d)

All molecules have sp3d hybridization and 3 bond pair + 2 lone pairs. Hence all have identical stucture (T-shape).

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