Verified Solution • 2025–26 Session moderate

QJEEM14Phf888: JEE Main 2014 Physics - Class 12 JEEM14Phf888 Solution: Hydrogen , Deuterium , singly ionised Helium and doubly ionised …

Hydrogen (1H1)\left( {{}_1{H^1}} \right) , Deuterium (1H2)\left( {{}_1{H^2}} \right) , singly ionised Helium (2He4)+{\left( {{}_2H{e^4}} \right)^ + } and doubly ionised lithium (3Li6)++{\left( {{}_3L{i^6}} \right)^{ + + }} all have one electron around the nucleus. Consider an electron transition from n=2n=2 to n=1.n=1. If the wavelengths of emitted radiation are λ1,λ2,λ3{\lambda _1},{\lambda _2},{\lambda _3} and λ4{\lambda _4} respectively then approximately which one of the following is correct?

Multiple Choice Options

  • A 4λ1=2λ2=2λ3=λ44{\lambda _1} = 2{\lambda _2} = 2{\lambda _3} = {\lambda _4}
  • B λ1=2λ2=2λ3=λ4{\lambda _1} = 2{\lambda _2} = 2{\lambda _3} = {\lambda _4}
  • C λ1=λ2=4λ3=9λ4{\lambda _1} = {\lambda _2} = 4{\lambda _3} = 9{\lambda _4}
  • D λ1=2λ2=3λ3=4λ4{\lambda _1} = 2{\lambda _2} = 3{\lambda _3} = 4{\lambda _4}

Step-by-Step Verified Solution

Wave number 1λ=RZ2[1n12−1n2]{1 \over \lambda } = R{Z^2}\left[ {{1 \over {n_1^2}} - {1 \over {{n^2}}}} \right]

⇒λ∝1Z2\Rightarrow \lambda \propto {1 \over {{Z^2}}}

By question n=1n=1 and n1=2{n_1} = 2

Then, λ1=λ2=4λ3=9λ4{\lambda _1} = {\lambda _2} = 4{\lambda _3} = 9{\lambda _4}

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