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QJEEM12Chc705: JEE Main 2012 Chemistry - Class 12 JEEM12Chc705 Solution: In the given transformation, which of the following is the most …

In the given transformation, which of the following is the most appropriate reagent ?

AIEEE 2012 Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 211 English

Multiple Choice Options

  • A NH2NH2,OHΘN{H_2}N{H_2},\mathop {OH}\limits^\Theta
  • B Zn−Hg/HClZn - Hg/HCl
  • C Na,Liq NH3Na,Liq\,N{H_3}
  • D NaBH4NaB{H_4}

Step-by-Step Verified Solution

Aldehydes and ketones can be reduced to hydrocarbons by the action (i)(i) of amalgamated zinc and concentrated hydrochloric acid (Clemmensen reduction), or (b)(b) of hydrazine (NH2NH2)\left( {N{H_2}N{H_2}} \right) and a strong base like NaOH,KOHNaOH,KOH or potassium tert-butoxide in a high-boiling alcohol like ethylene glycol or triethylene glycol (Wolf-Kishner reduction )

AIEEE 2012 Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 211 English Explanation

−OH-OH group and alkene are acid - sensitive groups so clemmensen reduction can not be used. Acid sensitive substrate should be reacted in the Wolf-Kishner reduction which utilise strongly basic conditions.

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