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QJEEM06Chc1f1: JEE Main 2006 Chemistry - Class 11 JEEM06Chc1f1 Solution: Which of the following chemical reactions depicts the oxidizing …

Which of the following chemical reactions depicts the oxidizing behaviour of H2SO4?

Multiple Choice Options

  • A NaCl + H2SO4 →\to NaHSO4 + HCl
  • B 2PCl5 + H2SO4 →\to 2POCl3 + 2HCl + SO2Cl2
  • C 2HI + H2SO4 →\to I2 + SO2 + 2H2O
  • D Ca(OH)2 + H2SO4 →\to CaSO4 + 2H2O

Step-by-Step Verified Solution

2HI−1+H2SO4+6→I20+SO2+4+2H2O2H{I^{ - 1}} + {H_2}\mathop {S{O_4}}\limits^{ + 6} \to I_2^0 + \mathop {S{O_2}}\limits^{ + 4} + 2{H_2}O

in this reaction oxidation number of SS is decreasing from +6+6 to +4+4 hence undergoing reduction and for HIHI oxidation Number of II is increasing from −1-1 to 00 hence undergoing oxidation therefore H2SO4{H_2}S{O_4} is acting as oxidising agent.

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